Home       Contact Us       Chinese
You are Here: home>>Research>>Research Highlights>>正文
Ca1-xRExAg1-ySb (RE = La, Ce, Pr, Nd, Sm; 0 ≤ x ≤1; 0 ≤ y ≤1): Interesting Structural Transformation and Enhanced High-Temperature Thermoelectric Performance
2014-03-21 20:51   审核人:

作者: Wang, Jian; Liu, Xiao-Cun; Xia, Sheng-Qing; Tao, Xu-Tang 

来源出版物: Journal of the American Chemical Society 卷: 135 期: 32 页: 11840-8 DOI: 10.1021/ja403653m 出版年: 2013-Aug-14 (Epub 2013 Aug 06) 

 

摘要: For materials used in high-temperature thermoelectric power generation, the choices are still quite limited. Here we demonstrate the design and synthesis of a new class of complex Zintl compounds, Ca1-xRExAg1-ySb (RE = La, Ce, Pr, Nd, Sm) (P63mc, No. 186, LiGaGe-type), which exhibit a high figure of merit in the high-temperature region. Compared with the parent structure that is based on CaAgSb (Pnma, No. 62, TiNiSi-type), an interesting structural relationship is established which suggests that important size and electronic effects govern the formation of these multinary phases. According to theoretical calculations, such a structural transformation from the orthorhombic TiNiSi-type to the hexagonal LiGaGe-type also corresponds to an obvious modification in the electronic band structure, which explains the observed significant enhancement of the related thermoelectric properties. For an optimized p-type material, Ca0.84Ce0.16Ag0.87Sb, a figure of merit of 0.7 can be achieved at 1079 K, which is comparable to that of Yb14MnSb11 at the same temperature. In addition, due to the excellent thermal stability and high electrical conductivity, these materials are very promising candidates for high-temperature thermoelectric power generation.  

关闭窗口
Copyright 2003-2015 State Key Lab of Crystal Materials Shandong University All Rights Reserved